High performance of metal-organic framework-derived catalyst supported by tellurium nanowire for oxygen reduction reaction

被引:14
作者
Wu, Cheng-Hao [1 ]
Wang, Kai-Chin [1 ]
Chang, Sun-Tang [1 ]
Chang, Yu-Chung [1 ]
Chen, Hsueh-Yu [1 ]
Yamanaka, Ichiro [2 ]
Chiang, Tai-Chin [3 ]
Huang, Hsin-Chih [3 ]
Wang, Chen-Hao [1 ]
机构
[1] Natl Taiwan Univ Sci & Technol, Dept Mat Sci & Engn, Taipei 10607, Taiwan
[2] Tokyo Inst Technol, Dept Appl Chem, Tokyo 1528552, Japan
[3] Natl Taiwan Univ Sci & Technol, Global Dev Engn Program, Taipei 10607, Taiwan
关键词
Nanowire tellurium; Metal-organic framework; Zeolitic imidazolate framework-67; Oxygen reduction reaction; Catalyst; NITROGEN-DOPED GRAPHENE; WALLED CARBON NANOTUBES; POROUS CARBON; ELECTROCATALYTIC ACTIVITY; ASSISTED SYNTHESIS; GRAPHITIC LAYERS; EFFICIENT; NANOPARTICLES; NANOFIBERS; OXIDE;
D O I
10.1016/j.renene.2020.05.114
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, a tellurium nanowire (NwTe) structure was synthesized as a template, and then a nanoscale zeolitic imidazolate framework 67 (Nano-Z67) was subsequently grown on it, denoted as Nano-Z67/NwTe. After pyrolyzed at a high temperature, the coordinated cobalt ion of Nano-Z67 and NwTe were transferred into the CoTe nanorods, which were encapsulated by a nitrogen-containing carbon nanowire (CN). The Nano-Z67/NwTe catalyzes the oxygen reduction reaction (ORR) with the electron-transfer number of 3.997 which is high than that of Pt/C with 3.995. The high ORR activity of Nano-Z67/NwTe attributed to the cobalt-nitrogen bond, carbon-nitrogen bond, and the NwTe-templated specific morphology, in which the CN serves as the conductive channel for electron transport. Remarkably, Nano-Z67/NwTe-750 not only demonstrates competitive performance compared with the Pt/C catalyst but also excellent stability. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页码:324 / 331
页数:8
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