Microwave synthesis and electrochemical properties of LiCo1-xMxO2 (M = Al and Mg) cathodes for Li-ion rechargeable batteries

被引：34
作者：
Elumalai, P
Vasan, HN [1 ]
Munichandraiah, N
机构：
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
来源：
JOURNAL OF POWER SOURCES | 2004年 / 125卷 / 01期
关键词：
Li-ion battery; cathodes; aluminum and magnesium substitution; microwave synthesis; discharge capacity;
D O I：
10.1016/S0378-7753(03)00815-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Single phase LiCo1-xMxO2 (M = Al and Mg) cathode materials for Li-ion batteries are synthesized by microwave dielectric heating with a reaction time less than 20 min. Aluminium forms solid solutions up to a composition of x = 0.5 and magnesium up to x = 0.2. Lattice constants are found to vary with the composition. The compounds are electrochemically active with good discharge capacity. (C) 2003 Elsevier B.V. All rights reserved.
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页码：77 / 84
页数：8
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