Di-μ-chlorido-bis{chlorido[2-(2-furyl-methyliminomethyl)pyridine-κ2N,N′]nickel(II)}

被引:1
作者
Xia, Dong-Sheng [1 ]
Chen, Wu [1 ]
Tang, Xin-Long [1 ]
Zeng, Qing-Fu [1 ]
机构
[1] Wuhan Univ Sci & Engn, Minist Educ, Engn Res Ctr Clean Prod Text Printing, Wuhan 430073, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808015183
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyridine N atoms of the Schiff base ligand, and by one terminal and two bridging Cl atoms. The Ni center dot center dot center dot Ni distance is 3.506 (2) angstrom. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Ni atom.
引用
收藏
页码:M836 / U977
页数:8
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