Solubility of Carbon Dioxide in Strongly Basic Ionic Liquid

被引：4

作者：

Sung, Jun Kyung ^{[3
]}

Kim, Sung Hyun ^{[4
]}

Cheong, Minserk ^{[1
,2
]}

Baek, Ilhyun ^{[3
]}

机构：

[1] Kyung Hee Univ, Dept Chem, Seoul 130701, South Korea

[2] Kyung Hee Univ, Res Inst Basic Sci, Seoul 130701, South Korea

[3] Korea Atom Energy Res Inst, Climate Change Technol Res Div, Taejon 305343, South Korea

[4] Korea Univ, Dept Chem Engn, Seoul 136701, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2010年 / 31卷 / 10期

关键词：

Strongly basic ionic liquid; Carbon dioxide capture; Phenolate-based ionic liquid; CO2; solubility; CO2; ABSORPTION;

D O I：

10.5012/bkcs.2010.31.10.2797

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low CO2 solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving CO2 absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [C-n-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [Cn-mim]OPh can be easily synthesized from corresponding [C-n-mim]Cl and sodium phenoxide and has been found to be good CO2 absorbents.

引用

页码：2797 / 2800

页数：4

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