Dissolved organic carbon loading from the field to watershed scale in tile-drained landscapes

Subsurface tile drains influence watershed fluxes of nitrogen, phosphorus, and pesticides, but few studies have examined the role of subsurface tile drains and drainage water management practices on watershed dissolved organic carbon (DOC) export. The objective of this study was therefore to quantify the contribution of subsurface tile drains to watershed DOC export and to evaluate the effect of drainage water management of DOC concentrations and loads in tile-drained fields. Discharge and DOC concentration were measured at the outlet of an agricultural headwater watershed (3.9 km(2)) in Ohio, USA and all of the subsurface tile drains (6 total) within the watershed over an 8-year period. Results showed that DOC concentration in both subsurface tile drains and stream water were highly variable (0.1-44.4 mg L-1), with mean DOC concentrations ranging from 5.7 to 8.2 mg L-1. Intra-annual variability in subsurface tile drain and watershed hydrology yielded seasonal differences in DOC loading. Over the study period, 81.7% and 92.4% of watershed and subsurface tile drain DOC loading, respectively, occurred during 20% of the time, typically during winter and spring high flow events. Mean annual DOC loading from the drainage network was 19.6 kg ha(-1), while mean annual DOC loading at the watershed outlet was 43.9 kg ha(-1). On average, subsurface tile drainage comprised 33% of monthly watershed DOC export (<1-82%). Implementing drainage water management at one of the subsurface tile drains decreased discharge (179 mm; 22%) and DOC loading (6.8 kg ha(-1); 26%) compared to an adjacent free draining subsurface tile drain. Findings from this study demonstrate the utility of simultaneously monitoring solute fluxes from both field and watershed scales, and indicate that subsurface tile drains are a significant source of DOC to headwater agricultural streams. Further, results suggest that drainage water management can significantly decrease DOC losses from tile-drained fields. Published by Elsevier B.V.