Computational study of the thermal rearrangement of acetoxy(methoxy) carbene

被引：5
|
作者：
Czardybon, W [1 ]
Warkentin, J [1 ]
Werstiuk, NH [1 ]
机构：
[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2005年 / 18卷 / 06期
关键词：
acetoxy(methoxy)carbene; carbene; concerted; computation; rearrangement;
D O I：
10.1002/poc.899
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Thermolysis of 2-acetoxy-2-methoxy-5,5-dimethyl-Delta(3)- 1,3,4-oxadiazoline affords acetoxy(methoxy)carbene. Thermal rearrangement of acetoxy(methoxy)carbene to methyl pyruvate is a concerted 1,2-migration, avoiding a potential radical-pair mechanism. Copyright (c) 2005 John Wiley & Sons, Ltd.
引用
收藏
页码：486 / 490
页数：5
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