Compatibility effects of modified montmorillonite on elastic and viscoelastic properties of nano-reinforced Poly(lactic acid): Experimental and modeling study

被引:5
作者
Gelineau, P. [1 ]
Weigand, S. [2 ]
Cauvin, L. [1 ]
Bedoui, F. [1 ]
机构
[1] Univ Technol Compiegne, Sorbonne Univ, Roberval UMR CNRS 7337, Compiegne, France
[2] Northwestern Univ, DND CAT Synchrotron Res Ctr, Anl Argonne, IL USA
关键词
Polymer-matrix nanocomposites (PMnC); Mechanical properties; Micro-structures; Micromechanics; Elasticity; Viscoelasticity; PLASTIC-DEFORMATION; TEXTURE EVOLUTION; NANOCOMPOSITES; BEHAVIOR; SIMULATION; PHASE; MMT;
D O I
10.1016/j.polymertesting.2018.06.020
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper aims to highlight the effects of the compatibility between nano-clay platelets and polymer matrix and capability of combined approaches (experimental and modeling) to capture the visco-elastic properties of the studied materials. In this context, a study, as complete as possible, is conducted through microstructural observation, mechanical characterization and micromechanical modeling. Nano-clay reinforced Poly(lactic acid) blends with different modified nano-clay platelets (Cloisite 30B and Cloisite 93A) were prepared. The linear elastic and visco-elastic behaviors of nano-reinforced samples were characterized. And a combination of lenght-scale-sensitive experimental techniques helped to describe the micro-structure through different microstructural parameters. These parameters were used as input into a viscoelastic micromechanical model. Comparison between experimental data (Complex, loss and storage moduli) and model predictions were in good agreement.
引用
收藏
页码:441 / 448
页数:8
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