Synthesis and crystal structures of lithium and potassium triazenide complexes

被引：58
作者：
Gantzel, P
Walsh, PJ [1 ]
机构：
[1] San Diego State Univ, Dept Chem, San Diego, CA 92182 USA
[2] Univ Calif San Diego, Ctr Struct Determinat, La Jolla, CA 92037 USA
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 14期
关键词：
D O I：
10.1021/ic9802911
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the 1,2,3-triazene Tol-N=N-NH-ToL with bases Li(N(SiMe3)(2), n-BuLi, KH, K(N(SiMe3)(2), and KO-t-Bu results in deprotonation of the triazene to give the lithium and potassium triazenide complexes. Both have been characterized structurally and have a dimeric core. However, the bonding of the triazenide to the metals is very different.
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页码：3450 / +
页数：3
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