Platinum-catalyzed intermolecular hydroamination of alkenes: Halide-anion-promoted catalysis

被引：95
作者：
Brunet, Jean-Jacques
Chu, Ngoc-Chau
Rodriguez-Zubiri, Mireia
机构：
[1] Univ Toulouse 3, CNRS, U8241, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] Inst Natl Polytech Toulouse, F-31077 Toulouse, France
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 30期
关键词：
alkenes; homogeneous catalysis; intermolecular hydroamination; ionic liquids; platinum;
D O I：
10.1002/ejic.200700737
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetraalkylphosphonium halides play the role of "promoters" for the previously unknown Pt-II-catalyzed hydroamination of alkenes. The promoting effect of these "cocatalysts" depends only upon their anionic moiety. The Pt-II/nBu(4)PBr system exhibits an unprecedented catalytic activity (aerobic conditions) for the hydroamination of ethylene and 1-hexene (regioselectivity > 95 %, Markovnikov).
引用
收藏
页码：4711 / 4722
页数：12
相关论文
共 125 条
[1]   PLATINUM COMPLEX CONTAINING A 4-MEMBERED RING [J].
ALNAJJAR, IM ;
GREEN, M ;
KERRISON, SJS ;
SADLER, PJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (07) :311-312
[2]   NUCLEOPHILIC-ATTACK ON OLEFINS COORDINATED TO PLATINUM .2. STABILITIES OF 2-AMMONIOETHANIDE SIGMA-ADDUCTS AND OF 5-CO-ORDINATE COMPLEXES [J].
ALNAJJAR, IM ;
GREEN, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (11) :1651-1656
[3]   Transition-metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes [J].
Alonso, F ;
Beletskaya, IP ;
Yus, M .
CHEMICAL REVIEWS, 2004, 104 (06) :3079-3159
[4]   Mechanistic and kinetic studies of palladium catalytic systems [J].
Amatore, C ;
Jutand, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 576 (1-2) :254-278
[5]   PLATINUM-PROMOTED CYCLIZATION REACTIONS OF AMINO-OLEFINS .1. CYCLIZATION OF 4-AMINOPENTENE AND RELATED COMPOUNDS [J].
AMBUEHL, J ;
PREGOSIN, PS ;
VENANZI, LM .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) :329-335
[6]   PLATINUM-PROMOTED CYCLIZATION REACTIONS OF AMINO OLEFINS .2. REGIOSELECTIVITY AND STEREOSELECTIVITY IN THE CYCLIZATION REACTIONS OF C-METHYL SUBSTITUTED PENT-4-ENYLAMINES [J].
AMBUEHL, J ;
PREGOSIN, PS ;
VENANZI, LM ;
CONSIGLIO, G ;
BACHECHI, F ;
ZAMBONELLI, L .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) :255-269
[7]   PLATINUM-PROMOTED CYCLIZATION OF 4-PENTENYLAMINE [J].
AMBUHL, J ;
PREGOSIN, PS ;
VENANZI, LM ;
UGHETTO, G ;
ZAMBONELLI, L .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (05) :369-369
[8]   Platinum-catalyzed formation of quinolines from anilines.: Aliphatic α-C-H activation of alkylamines and aromatic ortho-C-H activation of anilines [J].
Anguille, Stephane ;
Brunet, Jean-Jacques ;
Chu, Ngoc Chau ;
Diallo, Ousmane ;
Pages, Carole ;
Vincendeau, Sandrine .
ORGANOMETALLICS, 2006, 25 (12) :2943-2948
[9]  
[Anonymous], SURVEY IND CHEM
[10]  
[Anonymous], [No title captured]
12345678910