Facile synthesis of nanographene sheet hybrid α-MnO2 nanotube and nanoparticle as high performance electrode materials for supercapacitor

We have synthesized nanographene sheet (NGs) hybrid alpha-MnO2 nanotube (MTGs) and alpha-MnO2 nanoparticle (MPGs) by a joint method of burn-quench and hydrothermal. The NGs are prepared by directly reverting CO2 through a burn-quench method. The results indicate that these nano-carbons can easily react with KMnO4 to produce MPGs even at 40 degrees C and MTGs at 140 degrees C, respectively. The electrochemical measurements show the MTGs and MPGs have excellent electrochemical properties as supercapacitor electrode materials. The specific capacitance values for the MPGs and MTGs can get up to about 171.3 and 290.6 F g(-1) at current density of 1 A g(-1) in 1 M Na2SO4 electrolyte, respectively. Moreover, after 3000 cycles at a rate of 1 A g(-1), the corresponding specific capacitances are 150.6 F g(-1) for MPGs and 265.4 F g(-1) for MTGs materials, which reveals the good retention of capacity upon cycling. (C) 2015 Elsevier B.V. All rights reserved.