Water-soluble SG1-based alkoxyamines: A breakthrough in controlled/living free-radical polymerization in aqueous dispersed media

被引：117

作者：

Charleux, Bernadette ^{[1
]}

Nicolas, Julien ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Polymer, CNRS, UMR 7610, F-75252 Paris 05, France

来源：

POLYMER | 2007年 / 48卷 / 20期

关键词：

alkoxyamine; nitroxide-mediated controlled/living free-radical polymerization; emulsion polymerization;

D O I：

10.1016/j.polymer.2007.07.031

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This feature article describes the application of nitroxide-mediated controlled/living free-radical polymerization in aqueous dispersed systems such as miniemulsion and emulsion polymerizations. It mainly focuses on the acyclic nitroxide SG1 with derived alkoxyamines and aims to show how the recent development of new water-soluble species has allowed a true emulsion polymerization process to be successfully implemented and block copolymers to be created directly in latex particles. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：5813 / 5833

页数：21

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