Di-μ-chloro-bis{chloro[3,5-dimethyl-1-(thiocarbamoyl)pyrazole-κ2N2,S]cadmium(II)}

被引:5
作者
Evans, IR
Szécsényi, KM
Leovac, VM
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Novi Sad, Fac Sci, YU-21000 Novi Sad, Serbia Monteneg, Serbia
关键词
D O I
10.1107/S1600536805006173
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, [Cd2Cl4( C6H9N3S)(2)], has been determined. The compound is isomorphous with the previously reported Cu-II and Co-II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atoms. The structure is stabilized by a two-dimensional network of hydrogen bonds involving the terminal Cl atoms as acceptors and thiocarbamoyl group N atoms as donors.
引用
收藏
页码:M641 / M643
页数:3
相关论文
共 17 条
[1]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[2]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[3]   CRYSTALS version 12: software for guided crystal structure analysis [J].
Betteridge, PW ;
Carruthers, JR ;
Cooper, RI ;
Prout, K ;
Watkin, DJ .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1487-1487
[4]  
*BRUK AXS INC, 1999, SMART VERS 5 049 SAI
[5]  
DOWTY E, 2000, ATOMS VERS 5 1
[6]   Transition metal complexes with pyrazole based ligands, part 18: new binuclear Cu(I), Cu(II) and Co(II) complexes with 3,5-dimethyl-l-thiocarboxamide pyrazole: synthesis, structural and magnetic studies [J].
Evans, IR ;
Howard, JAK ;
Howard, LEM ;
Evans, JSO ;
Jacimovic, ZK ;
Jevtovic, VS ;
Leovac, VM .
INORGANICA CHIMICA ACTA, 2004, 357 (15) :4528-4536
[7]   Synthesis, characterization and crystal structure of a novel Ni(II) complex, Ni(L-H)2 (L=3,5-dimethyl-1-thiocarboxamidopyrazole) [J].
Evans, IR ;
Howard, JAK ;
Szécsényi, KM ;
Leovac, VM ;
Jacimovic, ZK .
JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (06) :469-476
[8]   Transition metal complexes with pyrazole-derived ligands.: X.: [Zn(CH3COO)2L2]•-2MeOH (L=3-amino-5-phenylpyrazole) [J].
Jacimovic, ZK ;
Tomic, ZD ;
Bogdanovic, GA ;
Iveges, EZ ;
Leovac, VM .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1999, 55 :1769-1771
[9]   Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-κ2N2,N)cobalt(III) [J].
Jacimovic, ZK ;
Tomic, ZD ;
Giester, G ;
Leovac, VM .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 :M381-M383
[10]  
KOVACS A, 2005, UNPUB NEW J CHEM