Radical Polymerization of Alkyl 2-Cyanoacrylates

被引：48

作者：

Duffy, Cormac ^{[1
,2
]}

Zetterlund, Per B. ^{[3
]}

Aldabbagh, Fawaz ^{[2
,4
]}

机构：

[1] Henkel Ireland Operat & Res Ltd, Dublin 24, Ireland

[2] Natl Univ Ireland Galway, Sch Chem, Univ Rd, Galway H91 TK33, Ireland

[3] Univ New South Wales, Sch Chem Engn, CAMD, Sydney, NSW 2052, Australia

[4] Kingston Univ, Sch Life Sci Pharm & Chem, Dept Pharm, Penrhyn Rd, Kingston Upon Thames KT1 2EE, Surrey, England

来源：

MOLECULES | 2018年 / 23卷 / 02期

关键词：

cyanoacrylate; instant adhesives; super glue; polymerization; radical; METHYL ALPHA-CYANOACRYLATE; PROPAGATION RATE COEFFICIENTS; EVALUATED RATE COEFFICIENTS; N-BUTYL CYANOACRYLATE; RING-OPENING POLYMERIZATION; ABSOLUTE RATE CONSTANTS; ANIONIC-POLYMERIZATION; THERMAL-DEGRADATION; POLYISOBUTYLCYANOACRYLATE NANOCAPSULES; POLY(ALKYL ALPHA-CYANOACRYLATES);

D O I：

10.3390/molecules23020465

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Cyanoacrylates (CAs) are well-known fast-setting adhesives, which are sold as liquids in the presence of stabilizers. Rapid anionic polymerization on exposure to surface moisture is responsible for instant adhesion. The more difficult, but synthetically more useful radical polymerization is only possible under acidic conditions. Recommendations on the handling of CAs and the resulting polymers are provided herein. In this review article, after a general description of monomer and polymer properties, radical homo- and copolymerization studies are described, along with an overview of nanoparticle preparations. A summary of our recently reported radical polymerization of CAs, using reversible addition-fragmentation chain transfer (RAFT) polymerization, is provided.

引用

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