Dielectric relaxation and predominance of NSPT and OLPT conduction processes in Ba0.9Sr0.1TiO3

被引：5

作者：

Zaitouni, H. ^{[1
]}

Hajji, L. ^{[1
]}

Choukri, E. ^{[1
]}

Mezzane, D. ^{[1
]}

Abkhar, Z. ^{[1
]}

Essaleh, L. ^{[1
]}

Alimoussa, A. ^{[1
]}

El Marssi, M. ^{[2
]}

Luk'yanchuk, I. A. ^{[2
]}

机构：

[1] Cadi Ayyad Univ, Lab Condensed Matter & Nanostruct LMCN, Fac Sci & Technol, Dept Appl Phys, Marrakech, Morocco

[2] Univ Picardie Jules Verne, LPMC, 33 Rue St Leu, F-80039 Amiens, France

来源：

SUPERLATTICES AND MICROSTRUCTURES | 2019年 / 127卷

基金：

欧盟地平线“2020”;

关键词：

BST; Ferroelectric; Conductive relaxation process; NSPT; OLPT; Impedance spectroscopy; TITANATE THIN-FILMS; MICROWAVE;

D O I：

10.1016/j.spmi.2017.11.060

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We investigate the relaxation and conduction mechanism of Ba0.90Sr0.10TiO3 (BST) ceramic, synthesized by the solid state reaction method. The dielectric and relaxation properties are analyzed in the temperature range of 380-450 degrees C with alternative current in the frequency range of 20 Hz-1MHz. Variation of dielectric constant, epsilon', with temperature shows a normal ferroelectric transition at T-c = 95 degrees C with a weak degree of diffuseness. The modified Cole Cole equation is used to describe all contributions to the relaxation mechanism. The frequency exponent m(omega,T) deduced from experimental data of the dielectric loss (epsilon '') as m(omega, T) = (partial derivative ln epsilon ''/partial derivative ln omega)(T) shows a temperature and frequency dependence. Two conduction process are observed: non-overlapping small-polaron tunneling (NSPT) at low frequencies and overlapping large polaron tunneling (OLPT) at high frequencies. The analysis of Nyquist plots reveals also the presence of two contributions, who which the activation energies have been calculated. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：176 / 185

页数：10

共 18 条

[1] BST solid solutions, temperature evolution of the ferroelectric transitions [J].

Alexandru, H. V. ;

Berbecaru, C. ;

Ioachim, A. ;

Nedelcu, L. ;

Dutu, A. .

APPLIED SURFACE SCIENCE, 2006, 253 (01) :354-357

[2]

[Anonymous], 1983, DIELECTRIC RELAXATIO

[3] General susceptibility functions for relaxations in disordered systems [J].

Bergman, R .

JOURNAL OF APPLIED PHYSICS, 2000, 88 (03) :1356-1365

[4]

Carlson C. M., 2000, J APPL PHYS LETT, V76, P920

[5] Pyroelectric properties in sol-gel derived barium strontium titanate thin films using a highly diluted precursor solution [J].

Cheng, JG ;

Tang, J ;

Chu, JH ;

Zhang, AJ .

APPLIED PHYSICS LETTERS, 2000, 77 (07) :1035-1037

[6] Dielectric and ferroelectric properties of BST ceramics obtained by a hydrothermally assisted complex polymerization method [J].

Cirkovic, Jovana ;

Vojisavljevic, Katarina ;

Nikolic, Nenad ;

Vulic, Predrag ;

Brankovic, Zorica ;

Sreckovic, Tatjana ;

Brankovic, Goran .

CERAMICS INTERNATIONAL, 2015, 41 (09) :11306-11313

[7] Dispersion and absorption in dielectrics I. Alternating current characteristics [J].

Cole, KS ;

Cole, RH .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351

[8] AC CONDUCTION IN AMORPHOUS-CHALCOGENIDE AND PNICTIDE SEMICONDUCTORS [J].

ELLIOTT, SR .

ADVANCES IN PHYSICS, 1987, 36 (02) :135-218

[9] USE OF CONDUCTION MODELS IN THE STUDY OF LOW-TEMPERATURE CARBONS [J].

GIUNTINI, JC ;

ZANCHETTA, JV .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1979, 34 (03) :419-424

[10] Barium strontium titanate-based perovskite materials for microwave applications [J].

Ioachim, A. ;

Toacsan, M. I. ;

Banciu, M. G. ;

Nedelcu, L. ;

Vasiliu, F. ;

Alexandru, H. V. ;

Berbecaru, C. ;

Stoica, G. .

PROGRESS IN SOLID STATE CHEMISTRY, 2007, 35 (2-4) :513-520

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