Design and post-functionalisation of ordered mesoporous zirconia thin films

Bidimensional hexagonal or centred-rectangular mesoporous zirconia thin films have been reproducibly prepared by evaporation-induced self-assembly (EISA), which are stable up to 300 degreesC, with pore size around 35 Angstrom; the films can be post-functionalised with organic ligands presenting different functions, opening a land of opportunities for the design of new hybrid mesostructured materials, based on the synergy of a transition metal oxide network and organic groups.