Structural and optical properties of zinc magnesium oxide nanoparticles synthesized by chemical co-precipitation

被引:51
作者
Rao, L. Srinivasa [1 ]
Rao, T. Venkatappa [2 ]
Naheed, Sd. [3 ]
Rao, P. Venkateswara [4 ]
机构
[1] VNR Vignano Jyothi Inst Engn & Technol, Ctr Nanosci & Technol, Dept Humanities & Sci Phys, Hyderabad 500OSO, Telangana, India
[2] NITW, Dept Phys, Warangal 506004, Telangana, India
[3] DK Jr Coll Girls, Nellore 524004, Andhra Prades, India
[4] Univ West Indies, Dept Phys, Mona Campus, Kingston 7, Jamaica
关键词
Nanoparticles; XRD; Optical band gap; IR spectra; DOPED ZNO NANOPARTICLES; MAGNETIC-PROPERTIES; SOLAR-CELLS; THIN-FILMS; PHOTOLUMINESCENCE; FTIR; MICROSTRUCTURE; CONDUCTIVITY; TEMPERATURE; EFFICIENCY;
D O I
10.1016/j.matchemphys.2017.09.048
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
By chemical co-precipitation method a series of ZnMgO nanoparticles were synthesized with the particular composition (1-x)ZnO-xMgO (where 0 <= x <= 2, all are in mol%). XRD spectra recorded at room temperature of these samples have shown the typical peaks of the ZnO hexagonal wurtzite structure, such as (1 0 0), (0 0 2), (1 0 1) etc. With the increasing concentration of MgO, the blue shift is attained in the absorption band of ZnO. Due to the Moss-Bustein effect the optical band gap has been widened by shifting towards higher frequency side as the concentration of MgO added progressively in the ZnO. The IR spectra revealed structural modifications in the stretching vibrations of Zn-O units as a function of MgO. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:133 / 140
页数:8
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