Inherently Chiral Calixarenes: Synthesis, Optical Resolution, Chiral Recognition and Asymmetric Catalysis

被引：105

作者：

Li, Shao-Yong ^{[2
]}

Xu, Yao-Wei ^{[1
]}

Liu, Jun-Min ^{[1
]}

Su, Cheng-Yong ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Tianjin Med Univ, Coll Pharm, Tianjin 300070, Peoples R China

来源：

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES | 2011年 / 12卷 / 01期

基金：

中国国家自然科学基金;

关键词：

inherently chiral calixarene; synthesis; optical resolution; chiral recognition; asymmetric catalysis; INTRAMOLECULAR RING-CLOSURE; LOWER RIM; STEREOSELECTIVE-SYNTHESIS; CONFORMATIONAL ISOMERS; DERIVATIVES; LIGANDS; FLUORESCENT; INHIBITION; MOIETIES; DESIGN;

D O I：

10.3390/ijms12010429

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Inherently chiral calixarenes, whose chirality is based on the absence of a planar symmetry or an inversion center in the molecules as a whole through the asymmetric array of several achiral groups upon the three-dimensional calix-skeletons, are challenging and attractive chiral molecules, because of their potential in supramolecular chemistry. The synthesis and optical resolution of all varieties of inherently chiral calixarenes are systematically discussed and classified, and their applications in chiral recognition and asymmetric catalysis are thoroughly illustrated in this review.

引用

页码：429 / 455

页数：27

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