High-performance porous biochar from the pyrolysis of natural and renewable seaweed (Gelidiella acerosa) and its application for the adsorption of methylene blue

被引:190
作者
Ahmed, M. J. [1 ]
Okoye, P. U. [2 ]
Hummadi, E. H. [3 ]
Hameed, B. H. [4 ]
机构
[1] Baghdad Univ, Engn Coll, Dept Chem Engn, POB 47024, Baghdad, Iraq
[2] Shenyang Univ Technol, Sch Sci, Shenyang 110870, Liaoning, Peoples R China
[3] Univ Diyala, Coll Sci, Dept Biotechnol, Baqubah, Iraq
[4] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Penang, Malaysia
关键词
Seaweed; Porous biochar; Adsorption; Pyrolysis; Kinetics; SEWAGE-SLUDGE; TEA WASTE; KINETICS; REMOVAL; EQUILIBRIUM; DYE; THERMODYNAMICS; MECHANISMS; SURFACE; ACID;
D O I
10.1016/j.biortech.2019.01.054
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
A high-performance porous biochar adsorbent prepared by facile thermal pyrolysis of seaweed (Gelidiella acerosa) is reported. The textural characteristics of the prepared seaweed biochar (SWBC) and the performance in the adsorption of methylene blue (MB) dye were evaluated. The batch experiment for the adsorption of MB was conducted under different parameters, such as temperature, pH, and initial concentration of MB in the range of 25-400 mg/L. The developed SWBC exhibited a relatively high surface area, average pore size, and pore volume of 926.39 m(2)/g, 2.45 nm, and 0.57 cm(3)/g, respectively. The high surface area and pristine mineral constituents of the biochar promoted a high adsorption capacity of 512.67 mg/g of MB at 30 degrees C. The adsorption isotherm and kinetics data best fitted the Langmuir and pseudo-second-order equations. The results indicate that SWBC is efficient for MB adsorption and could be a potential adsorbent for wastewater treatment.
引用
收藏
页码:159 / 164
页数:6
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