Synthesis of PVP stabilized bimetallic nanoparticles for removal of azo based reactive dye from aqueous solution

被引：13

作者：

Kale, Ravindra D. ^{[1
]}

Kane, Prerana B. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Fibers & Text Proc Technol, Nathalal Parekh Marg, Bombay 400019, Maharashtra, India

来源：

SUSTAINABLE CHEMISTRY AND PHARMACY | 2018年 / 10卷

关键词：

Bimetallic; Kinetics; Reactive Black 5; Response surface methodology; ZERO-VALENT IRON; GRANULAR IRON; WASTE-WATER; BLACK; 5; REDUCTIVE DECHLORINATION; ZEROVALENT IRON; METHYLENE-BLUE; DEGRADATION; DECOLORIZATION; BIODEGRADATION;

D O I：

10.1016/j.scp.2018.11.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bimetallic iron-copper nanoparticles (Fe-Cu-NPs) were used for decolorization of C. I. Reactive Black effluent. NPs were capped using polyvinylpyrrolidone (PVP) to prevent them from agglomeration. The NPs were characterized by particle size analysis, TEM, EDX, XRD, and zeta potential. Decolorization parameters such as pH, dye concentration, nanoparticle concentration and duration of treatment were evaluated to determine the optimum reaction parameters using response surface modeling, and the kinetic study was also undertaken. Effect of the presence of salt and alkali in the effluent was also evaluated. Reaction products formed during dye decolorization were investigated by GCMS, FTIR, and SEM. These analyses indicated that chromatogenous groups from the dye decompose which leads to dye decolorization. Recycling of NPs was also analyzed. There was 97.86% reduction in dye along with the COD, and BOD lowering was achieved with minimal sludge generation.

引用

页码：153 / 162

页数：10

共 72 条

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