A novel metal-free and metallophthalocyanines containing four 19-membered dithiadiazadioxa macrocycles by microwave irradiation: Synthesis and characterization

被引：24

作者：

Biyikhoglu, Zekeriya ^{[1
]}

Kantekin, Halit ^{[1
]}

机构：

[1] Karadeniz Tech Univ, Dept Chem, Fac Arts & Sci, TR-61080 Trabzon, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 03期

关键词：

phthalocyanine; dithiadiazamacrocycle; phthalonitrile; macrocyclization; tosylation;

D O I：

10.1016/j.jorganchem.2007.11.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel tetrasubstituted metal-free phthalocyanine (5) and metallophtalocyanines (6, 7 and 8) bearing four 19-membered dithiadiazadioxa macrocyclic moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (4) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis, elemental analysis and MS spectral data. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：505 / 509

页数：5

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