Enhanced photocatalytic activity of TiO2 by polydimethylsiloxane deposition and subsequent thermal treatment at 800 °C

被引:21
作者
Jeong, Myung-Geun [1 ]
Seo, Hyun Ook [1 ]
Kim, Kwang-Dae [1 ]
Kim, Young Dok [1 ]
Lim, Dong Chan [2 ]
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Korea Inst Mat Sci, Mat Proc Div, Chang Won 641010, South Korea
关键词
Photocatalysis; Evaporation polydimethylsiloxane; Titanium Dioxide; Powders; Hydrophilic Interaction; Methylene Blue; ABSORPTION; ANATASE; OXIDE;
D O I
10.1016/j.tsf.2012.03.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A thin film of polydimethylsiloxane (PDMS) was coated on TiO2 nanoparticles (P-25, Dagussa), and surface structures of the thin films were analyzed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Furthermore, photocatalytic activity of PDMS-coated TiO2 samples with various annealing temperatures was determined using UV irradiation. We show that the 800 degrees C-annealed sample of PDMS-coated TiO2 showed a two-fold higher photocatalytic activity with respect to the bare TiO2. The enhanced photocatalytic activity was attributed to the greater hydrophilicity of the annealed PDMS coating. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:4929 / 4933
页数:5
相关论文
共 19 条
[1]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[2]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[3]   Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].
Chen, Xiaobo ;
Liu, Lei ;
Yu, Peter Y. ;
Mao, Samuel S. .
SCIENCE, 2011, 331 (6018) :746-750
[4]   The effect of surface OH-population on the photocatalytic activity of rare earth-doped P25-TiO2 in methylene blue degradation [J].
Du, P. ;
Bueno-Lopez, A. ;
Verbaas, M. ;
Almeida, A. R. ;
Makkee, M. ;
Moulijn, J. A. ;
Mul, G. .
JOURNAL OF CATALYSIS, 2008, 260 (01) :75-80
[5]   Photocatalytic reactivity for O2•- and OH• radical formation in anatase and rutile TiO2 suspension as the effect of H2O2 addition [J].
Hirakawa, Tsutomu ;
Yawata, Kenta ;
Nosaka, Yoshio .
APPLIED CATALYSIS A-GENERAL, 2007, 325 (01) :105-111
[6]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[7]   Oxidation of Si during the growth of SiOx by ion-beam sputter deposition:: In situ x-ray photoelectron spectroscopy as a function of oxygen partial pressure and deposition temperature [J].
Kim, Kyung Joong ;
Kim, Jeong Won ;
Yang, Moon-Seung ;
Shin, Jung Hoon .
PHYSICAL REVIEW B, 2006, 74 (15)
[8]   Enhancement of Photocatalytic Activity of TiO2 by High-Energy Electron-Beam Treatment Under Atmospheric Pressure [J].
Kim, Myoung Joo ;
Kim, Kwang-Dae ;
Tai, Wei Sheng ;
Seo, Hyun Ook ;
Luo, Yuan ;
Kim, Young Dok ;
Lee, Byung Cheol ;
Park, Ok Kyung .
CATALYSIS LETTERS, 2010, 135 (1-2) :57-61
[9]   Nanostructured Ti-M mixed-metal oxides:: Toward a visible light-driven photocatalyst [J].
Kubacka, A. ;
Fernandez-Garcia, M. ;
Colon, G. .
JOURNAL OF CATALYSIS, 2008, 254 (02) :272-284
[10]   Hydrothermal synthesis, characterization, and photocatalytic performance of silica-modified titanium dioxide nanoparticles [J].
Li, ZJ ;
Hou, B ;
Xu, Y ;
Wu, D ;
Sun, YH .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 288 (01) :149-154