Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles

被引：288

作者：

Zhao, Depeng

Wang, Rui ^{[1
]}

机构：

[1] Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Sch Basic Med Sci, Inst Biochem & Mol Biol,Sch Life Sci, Lanzhou 730000, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 06期

基金：

中国国家自然科学基金;

关键词：

ALPHA-HYDROXY PHOSPHONATES; HIGHLY ENANTIOSELECTIVE HYDROPHOSPHONYLATION; ALPHA; BETA-UNSATURATED N-ACYLPYRROLES; HETEROBIMETALLIC LANTHANOID COMPLEXES; DIALKYL PHOSPHINE OXIDES; AMINO PHOSPHONATES; CYCLIC IMINES; ORGANOPHOSPHORUS COMPOUNDS; AL(SALALEN) COMPLEX; TITANIUM ALKOXIDES;

D O I：

10.1039/c1cs15247e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metal-catalyzed asymmetric addition of phosphorus nucleophiles is one of the most efficient and reliable approaches for the construction of new carbon-phosphorus bonds. In recent years, great achievements have been made in this area, and many powerful methods have been developed for these transformations with high efficiency, low ligand loading and excellent selectivity. This tutorial review covers recent efforts in the constructions of P-C bonds through asymmetric additions of phosphorus nucleophiles including dialkyl phosphites, secondary phosphine oxides and secondary phosphines.

引用

页码：2095 / 2108

页数：14

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