A symmetric chiral liquid-crystalline twin exhibiting stable ferrielectric and antiferroelectric phases and a chirality-induced isotropic-isotropic liquid transition

被引:45
作者
Nishiyama, I
Yamamoto, J
Goodby, JW
Yokoyama, H
机构
[1] JST, Yokoyama Nanostructured Liquid Crystal Project, Tsukuba, Ibaraki 3002635, Japan
[2] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England
关键词
D O I
10.1039/b105268n
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this article we report the first example of a pair of symmetrically substituted chiral twin enantiomers that exhibit stable wide temperature range ferrielectric and antiferroelectric phases, and which have large tilt angles of over 45 degrees. In addition, both of the enantiomers exhibited an isotropic-isotropic liquid transition just above the transition to the liquid crystalline state.
引用
收藏
页码:2690 / 2693
页数:4
相关论文
共 19 条
[1]   NOVEL ANTIFERROELECTRIC LIQUID CRYSTALS WITH A TRIFLUOROMETHYL GROUP AT THE CHIRAL CENTER [J].
Aoki, Yoshio ;
Nohira, Hiroyuki .
FERROELECTRICS, 1996, 178 :213-220
[2]   Direct smectic A-smectic CA* phase transition [J].
Beaubois, F ;
Faye, V ;
Marcerou, JP ;
Nguyen, HT ;
Rouillon, JC .
LIQUID CRYSTALS, 1999, 26 (09) :1351-1357
[3]   Solution of the dark state problem in antiferroelectric liquid crystal displays [J].
D'havé, K ;
Rudquist, P ;
Lagerwall, ST ;
Pauwels, H ;
Drzewinski, W ;
Dabrowski, R .
APPLIED PHYSICS LETTERS, 2000, 76 (24) :3528-3530
[4]   ANTIFERROELECTRIC CHIRAL SMECTIC LIQUID-CRYSTALS [J].
FUKUDA, A ;
TAKANISHI, Y ;
ISOZAKI, T ;
ISHIKAWA, K ;
TAKEZOE, H .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (07) :997-1016
[5]   FERROELECTRIC, FERRIELECTRIC AND ANTIFERROELECTRIC PROPERTIES IN THE (R)-1-METHYLALKYL AND (S)-1-METHYLALKYL 4'-(4''-NORMAL-ALKOXYBENZOYLOXY)BIPHENYL-4-CARBOXYLATE LIQUID-CRYSTALS [J].
GOODBY, JW ;
PATEL, JS ;
CHIN, E .
JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (02) :197-207
[6]   HELICAL TWIST SENSE AND SPONTANEOUS POLARIZATION DIRECTION IN FERROELECTRIC SMECTIC LIQUID-CRYSTALS .1. [J].
GOODBY, JW ;
CHIN, E ;
LESLIE, TM ;
GEARY, JM ;
PATEL, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (16) :4729-4735
[7]   A NEW MOLECULAR ORDERING IN HELICAL LIQUID-CRYSTALS [J].
GOODBY, JW ;
WAUGH, MA ;
STEIN, SM ;
CHIN, E ;
PINDAK, R ;
PATEL, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) :8119-8125
[8]   Liquid-crystalline Abrikosov flux phase with an antiferroelectric structure [J].
Goodby, JW ;
Petrenko, A ;
Hird, M ;
Lewis, RA ;
Meier, J ;
Jones, JC .
CHEMICAL COMMUNICATIONS, 2000, (13) :1149-1150
[9]   Structure of the liquid-crystal ferrielectric phases as determined by ellipsometry [J].
Johnson, PM ;
Olson, DA ;
Pankratz, S ;
Nguyen, T ;
Goodby, J ;
Hird, M ;
Huang, CC .
PHYSICAL REVIEW LETTERS, 2000, 84 (21) :4870-4873
[10]   Isotropic cubic phase of 4′-n-pentadecyloxy-3′-nitrobiphenyl-4-carboxylic acid (ANBC-15):: DSC, microscopic and dynamic viscoelastic studies [J].
Kutsumizu, S ;
Yamaguchi, T ;
Kato, R ;
Yano, S .
LIQUID CRYSTALS, 1999, 26 (04) :567-573