Roughening of atomically flat diamond (111) surfaces by a hot HNO3/H2SO4 solution

被引:14
作者
Tokuda, Norio [1 ]
Umezawa, Hitoshi [2 ]
Ri, Sung-Gi [1 ,3 ]
Yamabe, Kikuo [4 ,5 ]
Okushi, Hideyo [1 ]
Yamasaki, Satoshi [1 ,4 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, High Temp Quantum Elect Grp, Tsukuba, Ibaraki 3058568, Japan
[2] Natl Inst Adv Ind Sci & Technol, Diamond Res Ctr, Tsukuba, Ibaraki 3058568, Japan
[3] Japan Sci & Technol Corp, CREST, Tokyo, Japan
[4] Univ Tsukuba, Inst Appl Phys, Tsukuba, Ibaraki 3058573, Japan
[5] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058571, Japan
基金
日本学术振兴会;
关键词
surface; morphology; oxidation; etching;
D O I
10.1016/j.diamond.2008.01.042
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A systematic investigation of the roughening of atomically flat diamond (111) surfaces by immersion in a hot mixture of HNO3/H2SO4 acids was performed using atomic force microscopy. Before the immersion the diamond surfaces were atomically flat, with single bilayer steps and terraces; surface roughness increased after the immersion in the hot acid mixture. This result suggests that surface oxidation by the hot acid mixture etches the surface causing surface roughening. (C) 2008 Elsevier B.V. All fights reserved.
引用
收藏
页码:486 / 488
页数:3
相关论文
共 12 条
[1]   THERMAL HYDROGENATION OF DIAMOND SURFACES STUDIED BY DIFFUSE REFLECTANCE FOURIER-TRANSFORM INFRARED, TEMPERATURE-PROGRAMMED DESORPTION AND LASER RAMAN-SPECTROSCOPY [J].
ANDO, T ;
ISHII, M ;
KAMO, M ;
SATO, Y .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (11) :1783-1789
[2]   VAPOR-PHASE OXIDATION OF DIAMOND SURFACES IN O2 STUDIED BY DIFFUSE-REFLECTANCE FOURIER-TRANSFORM INFRARED AND TEMPERATURE-PROGRAMMED DESORPTION SPECTROSCOPY [J].
ANDO, T ;
YAMAMOTO, K ;
ISHII, M ;
KAMO, M ;
SATO, Y .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (19) :3635-3640
[3]   Oxidative etching of diamond [J].
de Theije, FK ;
Roy, O ;
van der Laag, NJ ;
van Enckevort, WJP .
DIAMOND AND RELATED MATERIALS, 2000, 9 (3-6) :929-934
[4]   Atomic structure of diamond {111} surfaces etched in oxygen water vapor [J].
de Theije, FK ;
Reedijk, MF ;
Arsic, J ;
van Enckevort, WJP ;
Vlieg, E .
PHYSICAL REVIEW B, 2001, 64 (08)
[5]   THE EFFECT OF SURFACE-TREATMENT ON THE ELECTRICAL-PROPERTIES OF METAL CONTACTS TO BORON-DOPED HOMOEPITAXIAL DIAMOND FILM [J].
GROT, SA ;
GILDENBLAT, GS ;
HATFIELD, CW ;
WRONSKI, CR ;
BADZIAN, AR ;
BADZIAN, T ;
MESSIER, R .
IEEE ELECTRON DEVICE LETTERS, 1990, 11 (02) :100-102
[6]   Investigation of the effect of hydrogen on electrical and optical properties in chemical vapor deposited on homoepitaxial diamond films [J].
Hayashi, K ;
Yamanaka, S ;
Watanabe, H ;
Sekiguchi, T ;
Okushi, H ;
Kajimura, K .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (02) :744-753
[7]   Study of the effect of hydrogen on transport properties in chemical vapor deposited diamond films by Hall measurements [J].
Hayashi, K ;
Yamanaka, S ;
Okushi, H ;
Kajimura, K .
APPLIED PHYSICS LETTERS, 1996, 68 (03) :376-378
[8]   The oxidation of diamond: The geometry and stretching frequency of carbonyl on the (100) surface [J].
John, P ;
Polwart, N ;
Troupe, CE ;
Wilson, JIB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (22) :6600-6601
[9]   Oxygen adsorption on (111)-oriented diamond: A study with ultraviolet photoelectron spectroscopy, temperature-programmed desorption, and periodic density functional theory [J].
Loh, KP ;
Xie, XN ;
Yang, SW ;
Zheng, JC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (20) :5230-5240
[10]   Surface conductive layers on (111) diamonds after oxygen treatments [J].
Ri, Sung-Gi ;
Nebel, Christoph E. ;
Takeuchi, Daisuke ;
Rezek, Bohuslav ;
Tokuda, Norio ;
Yamasaki, Satoshi ;
Okushi, Hideyo .
DIAMOND AND RELATED MATERIALS, 2006, 15 (4-8) :692-697