Injection Molding Shrinkage and Mechanical Properties of Polypropylene Blends

被引:12
作者
Qi, Guo-Qiang [1 ]
Xu, Ya-Jun [1 ]
Yang, Wei [1 ]
Xie, Bang-Hu [1 ]
Yang, Ming-Bo [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
来源
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS | 2011年 / 50卷 / 09期
基金
中国国家自然科学基金;
关键词
injection molding; mechanical properties; polypropylene blends; shrinkage; PARAMETERS; WARPAGE;
D O I
10.1080/00222348.2011.583798
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polypropylene (PP) blends based on isotactic polypropylene (iPP), propylene-ethylene block copolymer (bPP), and propylene-ethylene random copolymer (rPP) were prepared by melt blending and the effects of content of bPP and rPP on the shrinkage during solidification and storage and mechanical properties of the blends were studied. It was found that the addition of polypropylene copolymer could effectively reduce the processing shrinkage of iPP and the lowest shrinkage of the blends was achieved at a loading of 2 wt% bPP or rPP. The flexural modulus and tensile strength of the blends decreased a little while the impact strength and elongation at break were improved greatly compared with those of iPP.
引用
收藏
页码:1747 / 1760
页数:14
相关论文
共 27 条
[1]  
Bain M.F., 1992, SPE ANTEC TECH PAPER, V38, P977
[2]   Putting the 'nano' into composites [J].
Dagani, R .
CHEMICAL & ENGINEERING NEWS, 1999, 77 (23) :25-+
[3]   Tailoring the physical properties of isotactic polypropylene through incorporation of comonomers and the precise control of stereo and regioregularity by metallocene catalysts [J].
De Rosa, Claudio ;
Aurienuna, Finizia ;
De Ballesteros, Odda Ruiz ;
Resconi, Luigi ;
Carnurati, Isabella .
CHEMISTRY OF MATERIALS, 2007, 19 (21) :5122-5130
[4]  
Delbarre P., 1991, SPE ANTEC TECH PAPER, V37, P301
[5]   Flow-induced crystallization of propylene/ethylene random copolymers [J].
Housmans, Jan-Willem ;
Peters, Gerrit W. M. ;
Meijer, Han E. H. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (03) :693-705
[6]   VOLUMETRIC EFFECTS IN THE INJECTION-MOLDING OF POLYMERS [J].
ISAYEV, AI ;
HARIHARAN, T .
POLYMER ENGINEERING AND SCIENCE, 1985, 25 (05) :271-278
[7]   The effects of epoxy resin nano particles on shrinkage behavior and thermal stability of talc-filled polypropylene [J].
Jahani, Yousef ;
Ehsani, Morteza .
POLYMER BULLETIN, 2009, 63 (05) :743-754
[8]   Effect of processing conditions on shrinkage in injection molding [J].
Jansen, KMB ;
Van Dijk, DJ ;
Husselman, MH .
POLYMER ENGINEERING AND SCIENCE, 1998, 38 (05) :838-846
[9]   As-molded shrinkage measurements on polystyrene injection molded products [J].
Jansen, KMB ;
Pantani, R ;
Titomanlio, G .
POLYMER ENGINEERING AND SCIENCE, 1998, 38 (02) :254-264
[10]   Maximum rate of crystallization and morphology of random propylene ethylene copolymers as a function of comonomer content up to 21 mol % [J].
Jeon, K. ;
Chiari, Y. L. ;
Alamo, R. G. .
MACROMOLECULES, 2008, 41 (01) :95-108