A Triptycene-Based Porous Organic Polymer that Exhibited High Hydrogen and Carbon Dioxide Storage Capacities and Excellent CO2/N2 Selectivity

被引：11
作者：
Lu, Xi-Long [1 ]
Zhou, Tian-You [2 ]
Wu, Doufeng [3 ]
Wen, Qiang [2 ]
Zhao, Xin [2 ]
Li, Qiaowei [3 ]
Xiang, Qun [1 ]
Xu, Jia-Qiang [1 ]
Li, Zhan-Ting [3 ]
机构：
[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, Shanghai 200032, Peoples R China
[3] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 05期
基金：
中国国家自然科学基金;
关键词：
porous organic polymers; H-2/CO2; adsorption; CO2/N-2; selectivity; SURFACE-AREA; MICROPOROUS POLYMERS; AROMATIC FRAMEWORK; TARGETED SYNTHESIS; GAS-STORAGE; CO2; CAPTURE; NETWORKS; H-2; POROSITY;
D O I：
10.1002/cjoc.201500181
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel porous organic polymer (POP) has been constructed through the condensation of triptycene tricatechol and 1,3,5-benzenetris(4-phenylboronic acid). This triptycene-based POP exhibited high H-2 uptake (up to 1.84 wt% at 77 K, 1 bar), large CO2 adsorption capacity (up to 18.1 wt% at 273K, 1 bar), and excellent CO2/N-2 adsorption selectivity (up to 120/1). The influence of solvent on the gas adsorption performance of the POP has also been investigated.
引用
收藏
页码：539 / 544
页数：6
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