Electrochemical behaviour of Alloy 600 tubing in thiosulphate solution

被引：46
作者：
Faichuk, M. G. [1 ]
Ramamurthy, S.
Lau, W. M. [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON, Canada
来源：
CORROSION SCIENCE | 2011年 / 53卷 / 04期
关键词：
Alloy; XPS; AES; EIS; Passive film; Stress corrosion; STRESS-CORROSION CRACKING; POINT-DEFECT MODEL; RAY PHOTOELECTRON-SPECTROSCOPY; HIGH-TEMPERATURE WATER; ANODIC PASSIVE FILMS; NICKEL-BASE ALLOYS; NI-CR ALLOYS; IMPEDANCE SPECTROSCOPY; OXIDE-FILMS; SENSITIZED ALLOY-600;
D O I：
10.1016/j.corsci.2011.01.011
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Electrochemical and surface properties of passive films formed on Alloy 600 in a thiosulphate solution were studied. Oxide films formed at various passive potentials contained a bilayer oxide, whose composition changed as a function of the applied potential resulting in a change in the impedance behaviour. Destabilisation of the oxide film at potentials within the passive region was observed, which was due to the breakdown of the oxide film and coincided with the loss of Cr within the passive film. In contrast, a higher degree of corrosion protection was obtained when the Cr content within the oxide film was elevated. (c) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1383 / 1393
页数：11
相关论文
共 47 条
  • [21] A POINT-DEFECT MODEL FOR ANODIC PASSIVE FILMS .2. CHEMICAL BREAKDOWN AND PIT INITIATION
    LIN, LF
    CHAO, CY
    MACDONALD, DD
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (06) : 1194 - 1198
  • [22] Effects of temperature and potential on the passive corrosion properties of alloys C22 and C276
    Lloyd, AC
    Shoesmith, DW
    McIntyre, NS
    Noël, JJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (04) : B120 - B130
  • [23] An electrochemical impedance spectroscopic study of the passive state on Alloy-22
    Macdonald, DD
    Sun, A
    [J]. ELECTROCHIMICA ACTA, 2006, 51 (8-9) : 1767 - 1779
  • [24] MACDONALD JR, 1987, IMPEDANCE SPECTROSCO, pCH4
  • [25] XPS and STM study of the growth and structure of passive films in high temperature water on a nickel-base alloy
    Machet, A
    Galtayries, A
    Zanna, S
    Klein, L
    Maurice, V
    Jolivet, P
    Foucault, M
    Combrade, P
    Scott, P
    Marcus, P
    [J]. ELECTROCHIMICA ACTA, 2004, 49 (22-23) : 3957 - 3964
  • [26] Surface modification of Inconel-600 by growth of a hydrous oxide film
    Marijan, D
    Vukovic, M
    Pervan, P
    Milun, M
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1998, 28 (01) : 96 - 102
  • [27] X-ray photoelectron spectroscopy and scanning tunneling microscopy study of passive films formed on (100) Fe-18Cr-13Ni single-crystal surfaces
    Maurice, V
    Yang, WP
    Marcus, P
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (03) : 909 - 920
  • [28] XPS STUDY OF INITIAL GROWTH OF OXIDE-FILMS ON INCONEL-600 ALLOY
    MCINTYRE, NS
    ZETARUK, DG
    OWEN, D
    [J]. APPLICATIONS OF SURFACE SCIENCE, 1978, 2 (01): : 55 - 73
  • [29] General corrosion of alloy 22: Experimental determination of model parameters from electrochemical impedance spectroscopy data
    McMillion, LG
    Sun, A
    MacDonald, DD
    Jones, DA
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (05): : 1129 - 1141
  • [30] THE CHEMICAL-COMPOSITION OF THE PASSIVE FILM ON FE-24CR AND FE-24CR-11MO STUDIED BY AES, XPS AND SIMS
    MISCHLER, S
    VOGEL, A
    MATHIEU, HJ
    LANDOLT, D
    [J]. CORROSION SCIENCE, 1991, 32 (09) : 925 - 944
12345