Magnetic molecular charge-transfer salts containing layers of water and tris(oxalato) ferrate(III) anions

被引：19
作者：
Martin, Lee [1 ]
Day, Peter [1 ]
Barnett, Sarah A. [2 ]
Tocher, Derek A. [2 ]
Horton, Peter N. [3 ]
Hursthouse, Mike B. [3 ]
机构：
[1] Royal Inst Great Britain, Davy Faraday Res Lab, London W1X 4BS, England
[2] UCL, Christopher Ingold Labs, Dept Chem, London W1CH 0AJ, England
[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 02期
关键词：
D O I：
10.1039/b711325k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We describe the synthesis, crystal structure and conducting properties of two new BEDT-TTF charge transfer salts of tris(oxalato) ferrate(III) containing slightly different numbers of water molecules, (BEDT-TTF)(12)[Fe(C(2)O(4))(3)](2)center dot xH(2)O [x = 15 (I) and 16 (II)]. I crystallizes in the monoclinic space group C2/c, a = 36.017(10), b = 30.880(10), c = 36.183(15) angstrom, alpha = 90, beta = 93.66(3), gamma = 90 degrees, V = 40 161(23) angstrom(3), T = 120(2) K, Z = 8, R1 = 0.0842 [F(2) > 2 sigma(F(2))]; II crystallizes in the same space group, a = 17.9695(15), b = 15.4988(13), c = 36.115(3) angstrom, alpha = 90, beta = 93.720(2), gamma = 90 degrees, V = 10037.1(14) angstrom(3), T = 150(2) K, Z = 4, R1 = 0.0673 [F(2) > 2 sigma(F(2))]. Electrical resistivity measurements show that I and II are semiconductors below 275 K.
引用
收藏
页码：192 / 196
页数：5
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