Preparation of pure N@C60

被引：0
|
作者：
Jakes, P [1 ]
Dinse, KP [1 ]
Meyer, C [1 ]
Harneit, W [1 ]
Weidinger, A [1 ]
机构：
[1] Tech Univ Darmstadt, D-64287 Darmstadt, Germany
来源：
FULLERENES AND NANOTUBES: THE BUILDING BLOCKS OF NEXT GENERATION NANODEVICES | 2003年 / 2003卷 / 15期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using multi-step High Performance Liquid Chromatography (HPLC) it was possible to prepare a chromatographically pure sample of N@C-60. Invoking EPR spectroscopy of solid samples prepared after each HPLC step, the increase of relative N@C-60 concentration could unambiguously be determined. The UV/Vis spectrum of N@C-60 is indistinguishable within experimental error from that of C-60, confirming negligible coupling between nitrogen in its atomic ground state and C-60 cage molecular wave functions.
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页码：537 / 542
页数：6
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