Interactions of lignin and LDPE during catalytic co-pyrolysis: Thermal behavior and kinetics study by TG-FTIR

被引：35

作者：

Tao, Liangliang ^{[1
]}

Ma, Xianming ^{[1
]}

Ye, Lihui ^{[1
]}

Jia, Jingwen ^{[1
]}

Wang, Lu ^{[1
]}

Ma, Peiyong ^{[2
]}

Liu, Jian ^{[1
,3
]}

机构：

[1] Hefei Univ Technol, Sch Food & Biol Engn, Hefei 230009, Anhui, Peoples R China

[2] Hefei Univ Technol, Sch Mech Engn, Hefei 230009, Anhui, Peoples R China

[3] Hefei Univ Technol, Minist Educ, Engn Res Ctr Bioproc, Hefei 230009, Peoples R China

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2021年 / 158卷

关键词：

Lignin; LDPE; Catalytic co-pyrolysis; TG-FTIR; Synergistic effect; DENSITY POLYETHYLENE; RICE STRAW; PLASTICS; BIOMASS; WASTE; BLENDS; DEGRADATION; HYDROGEN; FUELS;

D O I：

10.1016/j.jaap.2021.105267

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Thermal behavior and interaction of Low-density polyethylene (LDPE) and lignin with HZSM-5 as catalyst during catalytic co-pyrolysis were analyzed by thermogravimetric analyzer coupled with Fourier transform infrared spectrometer (TG-FTIR). The synergistic effect of lignin and hydrogen-rich LDPE decreased the starting temperature of pyrolysis and accelerated the pyrolysis rate. Kinetic analysis based on the Coats-Redfern method showed that HZSM-5 catalysis significantly decreased the reaction's activation energy. FTIR results also indicated that the composition of pyrolysis products shifted to more alkane and aromatics by co-feeding the lignin with LDPE and catalyst HZSM-5.

引用

页数：5

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