Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

被引：8

作者：

Morshedi, Mahbod ^{[1
]}

Amirnasr, Mehdi ^{[1
]}

Triki, Smail ^{[2
]}

Khalaji, Aliakbar Dehno ^{[3
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran

[2] Univ Bretagne Occidentale, CNRS, UMR 6521, F-29285 Brest, France

[3] Gorgan Univ Agr Sci & Nat Resources, Dept Sci, Gorgan 4918943464, Iran

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期

关键词：

N2S2; Schiff-base; Tridentate coordination mode; Copper (I) complex; X-ray crystal structure; SILVER(I) COORDINATION ARCHITECTURES; PYRIDYL DITHIOETHER LIGANDS; MONONUCLEAR COMPLEXES; HETEROCYCLIC THIOETHERS; CHEMISTRY; CHROMOPHORE; POLYMER; CAGE; BR;

D O I：

10.1007/s10870-010-9833-4

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca(2)dapte [Cu(ca(2)dapte)(NCS)], [ca(2)dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca(2)dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) , alpha = 89.385(7), beta = 68.527(7), gamma = 66.190(8)A degrees; V = 1425.8(2) (3), Z = 2, R = 0.0417, wR (2) = 0.0744.

引用

页码：39 / 43

页数：5

共 24 条

[1] Synthesis, characterization, and crystal structures of [Ag(ca2en)(PPh3)(X)] (X = N3, SCN) complexes
Amirnasr, Mehdi
Khalaji, Aliakbar Dehno
Falvello, Larry R.
Soler, Tatiana
[J]. POLYHEDRON, 2006, 25 (09) : 1967 - 1970
[2] [Anonymous], 1975, INT TABLES XRAY CRYS, VIV
[3] [Anonymous], CRYSALIS CCD 170
[4] [Anonymous], 1997, SHELX97 PROGRAMS CRY
[5] [Anonymous], 2002, CRYSALIS RED 170
[6] Complexes of Ag(I), Hg(I) and Hg(II) with multidentate pyrazolyl-pyridine ligands:: from mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate
Argent, Stephen P.
Adams, Harry
Riis-Johannessen, Thomas
Jeffery, John C.
Harding, Lindsay P.
Clegg, William
Harrington, Ross W.
Ward, Michael D.
[J]. DALTON TRANSACTIONS, 2006, 42 (42) : 4996 - 5013
[7] Synthesis and spectral studies on mononuclear complexes of chromium(III) and manganese(II) with 12-membered tetradentate N2O2, N2S2 and N4 donor macrocyclic ligands
Chandra, S
Kumar, R
[J]. TRANSITION METAL CHEMISTRY, 2004, 29 (03) : 269 - 275
[8] Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]
[9] Mononuclear and polynuclear copper(I) complexes with a new N,N',S-donor ligand and with structural analogies to the copper thionein core
Gennari, Marcello
Lanfranchi, Maurizio
Cammi, Roberto
Pellinghelli, Maria Angela
Marchio, Luciano
[J]. INORGANIC CHEMISTRY, 2007, 46 (24) : 10143 - 10152
[10] JOHNSON CK, 1985, ONL3794 ORTEP

← 1 2 3 →