Converting the role of LiClO4 from salting-in to salting-out in Diels-Alder reactions by solvent manipulation

被引：3
|
作者：
Deshpande, SS
Pawar, SS
Phalgune, U
Kumar, A [1 ]
机构：
[1] Natl Chem Lab, Div Phys Chem, Pune 411008, Maharashtra, India
[2] Natl Chem Lab, OCS Div, Pune 411008, Maharashtra, India
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2003年 / 16卷 / 09期
关键词：
Diels-Alder reaction; salting-out; salting-in; stereoselectivity; solubility;
D O I：
10.1002/poc.668
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The low yield of endo products of a Diels-Alder reaction in aqueous LiClO4 can be enhanced by using a simple solvent. manipulation. This report on the use of salt solutions opens up the possibility of creating effective conditions for Diels-Alder reactions. Copyright (C) 2003 John, Wiley Sons, Ltd.
引用
收藏
页码：633 / 635
页数：3
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