IR Spectrum and Structure of the Phenyl Cation

被引：37

作者：

Patzer, Alexander ^{[1
]}

Chakraborty, Shamik ^{[1
]}

Solca, Nicola ^{[1
]}

Dopfer, Otto ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Opt & Atomare Phys, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 52期

关键词：

carbocations; IR spectroscopy; phenyl cation; structure elucidation; INFRARED PHOTODISSOCIATION SPECTRA; GAS-PHASE; SPECTROSCOPY; ION; NITROGEN; GENERATION; CHEMISTRY; CLUSTERS; BENZENE; COMPLEX;

D O I：

10.1002/anie.201006357

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No way to hide: The IR spectrum of the phenyl cation, c-C6H 5+, has been derived by resonant IR photodissociation of weakly bound C6H5+·Ar clusters (see picture). The analysis provides the first spectroscopic characterization of this fundamental carbocation in the gas phase. The Ar ligand is used to probe the electrophilicity of the vacant nonbonding σ orbital of c-C 6H5+. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10145 / 10148

页数：4

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