An enantioselective two-component catalyst system: Rh-Pd-catalyzed allylic alkylation of activated nitriles

被引：268

作者：

Sawamura, M ^{[1
]}

Sudoh, M ^{[1
]}

Ito, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM & BIOL CHEM,KYOTO 60601,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 13期

关键词：

D O I：

10.1021/ja954223e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here a novel enantioselective reaction promoted by a two-component catalyst system consisting of two different transition metal complexes, in which the two catalysts activate their respective substrates and the resulting active species react in an enantioselective manner to produce an optically active compound. We have undertaken the study of the enantioselective allylic alkylation of the activated nitriles by employing a π-allypalladium(II) complex as an electrophile instead of the Michael acceptor.

引用

页码：3309 / 3310

页数：2

共 15 条

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