Pathway to high throughput, low cost indium-free transparent electrodes

被引:13
作者
Stapleton, Andrew J. [1 ]
Yambem, Soniya [2 ]
Johns, Ashley H. [1 ]
Gibson, Christopher T. [1 ]
Shearer, Cameron J. [1 ]
Ellis, Amanda V. [1 ]
Shapter, Joe G. [1 ]
Andersson, Gunther G. [1 ]
Quinton, Jamie S. [1 ]
Burn, Paul L. [2 ]
Meredith, Paul [2 ]
Lewis, David A. [1 ]
机构
[1] Flinders Univ S Australia, Flinders Ctr NanoScale Sci & Technol, Adelaide, SA 5001, Australia
[2] Univ Queensland, Ctr Organ Photon & Elect, Brisbane, Qld 4072, Australia
关键词
RAMAN-SPECTROSCOPY; THIN-FILMS; SILVER; NETWORKS;
D O I
10.1039/c5ta03248b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A roll-to-roll compatible, high throughput process is reported for the production of highly conductive, transparent planar electrode comprising an interwoven network of silver nanowires and single walled carbon nanotubes imbedded into poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS). The planar electrode has a sheet resistance of between 4 and 7 Omega square(-1) and a transmission of >86% between 800 and 400 nm with a figure of merit of between 344 and 400 Omega(-1). The nanocomposite electrode is highly flexible and retains a low sheet resistance after bending at a radius of 5 mm for up to 500 times without loss. Organic photovoltaic devices containing the planar nanocomposite electrodes had efficiencies of similar to 90% of control devices that used indium tin oxide as the transparent conducting electrode.
引用
收藏
页码:13892 / 13899
页数:8
相关论文
共 44 条
[11]  
Garnett EC, 2012, NAT MATER, V11, P241, DOI [10.1038/NMAT3238, 10.1038/nmat3238]
[12]   Press-transfer optically transparent electrodes fabricated from commercial single-walled carbon nanotubes [J].
Garoz-Ruiz, J. ;
Palmero, S. ;
Ibanez, D. ;
Heras, A. ;
Colina, A. .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 25 :1-4
[13]   Fully Solution-Processed Inverted Polymer Solar Cells with Laminated Nanowire Electrodes [J].
Gaynor, Whitney ;
Lee, Jung-Yong ;
Peumans, Peter .
ACS NANO, 2010, 4 (01) :30-34
[14]  
Giurgola S., 2007, LAS EL 2007 INT QUAN, DOI [10.1109/CLEOE-IQEC.2007.4386181., DOI 10.1109/CLEOE-IQEC.2007.4386181]
[15]   A Healable, Semitransparent Silver Nanowire-Polymer Composite Conductor [J].
Gong, Chaokun ;
Liang, Jiajie ;
Hu, Wei ;
Niu, Xiaofan ;
Ma, Sungwon ;
Hahn, H. Thomas ;
Pei, Qibing .
ADVANCED MATERIALS, 2013, 25 (30) :4186-4191
[16]   TCO/metal/TCO structures for energy and flexible electronics [J].
Guillen, C. ;
Herrero, J. .
THIN SOLID FILMS, 2011, 520 (01) :1-17
[17]   Silver nanowire/polyimide composite transparent electrodes for reliable flexible polymer solar cells operating at high and ultra-low temperature [J].
Guo, Xiaoyang ;
Liu, Xingyuan ;
Luo, Jinsong ;
Gan, Zhihong ;
Meng, Zhong ;
Zhang, Nan .
RSC ADVANCES, 2015, 5 (32) :24953-24959
[18]   Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells [J].
Hong, Wenjing ;
Xu, Yuxi ;
Lu, Gewu ;
Li, Chun ;
Shi, Gaoquan .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (10) :1555-1558
[19]   Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites [J].
Hu, Weili ;
Niu, Xiaofan ;
Li, Lu ;
Yun, Sungryul ;
Yu, Zhibin ;
Pei, Qibing .
NANOTECHNOLOGY, 2012, 23 (34)
[20]  
Kamyshny A., 2011, Open Appl. Phys. J., V4, P19, DOI [10.2174/1874183501104010019, DOI 10.2174/1874183501104010019]