Effects of Ni substitution on structural, dielectrical, and ferroelectric properties of chemical-solution-deposited multiferroic BiFeO3 films

被引:17
作者
Singh, S. K. [1 ]
Palai, R. [2 ]
Maruyama, K. [3 ]
Ishiwara, H. [1 ]
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Univ Puerto Rico, Dept Phys, San Juan, PR 00931 USA
[3] Fujitsu Labs Ltd, Atsugi, Kanagawa 2430197, Japan
关键词
D O I
10.1149/1.2912024
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Multiferroic thin films of Ni-substituted BiFeO(3) were grown by chemical-solution deposition on Pt/Ti/SiO(x)/Si(100) substrates. Films with up to 7.5 atom % Ni substitution showed a single perovskite phase with rhombohedral structure at room temperature, while films with 10 atom % Ni substitution showed a tetragonal-like crystal structure. Ni substitution of 2.5 atom % was effective in suppressing leakage current in the high-electric-field region with high polarization (72 mu C/cm(2)) and coercive field (340 kV/cm) when polarization vs electric field hysteresis loops were drawn at 20 kHz with a maximum electric field of 1100 kV/cm. (C) 2008 The Electrochemical Society.
引用
收藏
页码:G30 / G32
页数:3
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