Cobalt-Catalyzed Cycloamination: Synthesis and Photophysical Properties of Polycyclic N-Heterocycles

被引：36
作者：
Dong, Yu [1 ,2 ]
Yang, Jian [1 ,2 ]
Zhang, Hua [1 ,2 ]
Zhan, Xiao-Yu [1 ,2 ]
He, Shuai [3 ]
Shi, Zhi-Chuan [3 ]
Zhang, Xiao-Mei [1 ]
Wang, Ji-Yu [1 ]
机构：
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Southwest Minzu Univ, Chengdu 610041, Peoples R China
来源：
ORGANIC LETTERS | 2020年 / 22卷 / 13期
关键词：
C-H AMINATION; ACID; DERIVATIVES; CARBAZOLES; ANILINES; ACCESS;
D O I：
10.1021/acs.orglett.0c01753
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first earth-abundant cobalt-catalyzed cycloamination of indolylquinones and various (hetero)aromatic amine under ligand-free conditions for the synthesis of polycyclic N-heterocycles has been developed. The process allows facile access to polycyclic N-heterocycles with tolerance of chloride, bromide, amino, thio, etc. groups in moderate to high yields (up to 89%). In addition, The photophysical properties of the synthesized products were evaluated. These products exhibit interesting fluorescence properties, which is promising for fluorescent probes.
引用
收藏
页码：5151 / 5156
页数：6
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