Bimetallic nanoparticles supported ionic liquid as an effective heterogeneous nanocatalyst for green synthesis of chromenes under solvent-free conditions

被引:3
|
作者
Kazempour, Somayeh [1 ]
Naeimi, Hossein [1 ]
机构
[1] Univ Kashan, Dept Organ Chem, Fac Chem, Kashan 8731751167, Iran
关键词
bimetallic; chromene; ionic liquid; nanocatalyst; novel; CATALYST; HYDROGENATION; DERIVATIVES; REDUCTION; SERIES;
D O I
10.1002/aoc.6903
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this research, a novel bimetallic nanoparticles supported by 1,3-bis (triethoxysilylpropyl) imidazolium hydrogen sulfate ionic liquid (Ni.Cu@SiO2.BSPIm/HSO4) are designed and prepared, and its catalytic activity is investigated in organic reaction. The prepared nanocatalyst was characterized using Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray, thermogravimetric analysis, field emission scanning electron microscopy, and X-ray powder diffraction techniques. This catalyst exhibited great activity in the one-pot synthesis of chromene derivatives through condensation reaction. The products were obtained with high purity in high to excellent yields and short reaction times. The organic products were identified by melting points, FT-IR, and H-1 NMR analyses.
引用
收藏
页数:13
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