Immobilised molecular catalysts and the role of the supporting metal substrate

被引：29
作者：
Duncan, David A. [1 ]
Deimel, Peter S. [1 ]
Wiengarten, Alissa [1 ]
Han, Runyuan [1 ]
Acres, Robert G. [2 ]
Auwaerter, Willi [1 ]
Feulner, Peter [1 ]
Papageorgiou, Anthoula C. [1 ]
Allegretti, Francesco [1 ]
Barth, Johannes V. [1 ]
机构：
[1] Tech Univ Munich, Phys Dept E20, D-85748 Garching, Germany
[2] Sincrotrone Trieste, I-34149 Trieste, Italy
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 46期
关键词：
RUTHENIUM PORPHYRIN; HETEROGENEOUS CATALYSIS; AG(111); OXYGEN; EPOXIDATION; CONFORMATION; CHEMISTRY;
D O I：
10.1039/c5cc01639h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This work demonstrates that immobilising molecular catalysts on metal substrates can attenuate their reactivity. In particular, the reactivity towards molecular oxygen of both ruthenium tetraphenyl porphyrin (Ru-TPP) and its Ti analogue (Ti-TPP) on Ag(111) was studied as benchmark for the interaction strength of such metal-organic complexes with possible reactants. Here, Ru-TPP proves to be completely unreactive and Ti-TPP strongly reactive towards molecular oxygen; along with comparison to work in the literature, this suggests that studies into immobilised catalysts might find fruition in considering species traditionally seen as too strongly interacting.
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收藏
页码：9483 / 9486
页数：4
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