Domino metathesis of alkynyl substituted cycloolefins

被引：39
作者：
Rückert, A [1 ]
Eisele, D [1 ]
Blechert, S [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 31期
关键词：
metathesis; enynes; rearrangements; ruthenium;
D O I：
10.1016/S0040-4039(01)01003-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cycloolefins with N- and O-propargyl side chains were converted in good yields to disubstituted dihydropyrroles and dihydrofurans using Grubbs' catalyst in a sequence of enyne metathesis, RCM-ROM and CM. Olefins employed in the final CM step were ethylene and various monosubstituted alkenes. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：5245 / 5247
页数：3
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