Challenges in oxidation catalysis

被引：11

作者：

Buijs, W ^{[1
]}

机构：

[1] Delft Univ Technol, Fac Sci Appl, NL-2628 BL Delft, Netherlands

来源：

TOPICS IN CATALYSIS | 2003年 / 24卷 / 1-4期

关键词：

DOW-Phenol; acrylonitrile; NaY; cyclohexanone; CoAlPO; adipic acid; hydroxylamine; caprolactam; confinement;

D O I：

10.1023/B:TOCA.0000003078.34848.23

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

yFrom an industrial chemical perspective, successful oxidation catalysis poses three challenges: (1) use (di)oxygen, (2) avoid overoxidation of the substrate, and (3) overcome the lack of functionality in the feedstock. From the options discussed, confinement seems to be the most versatile way to meet all the needs of industrial oxidation catalysis.

引用

页码：73 / 78

页数：6

共 14 条

[1]

AGTERBERG F, 1996, THESIS LEIDEN U

[2] Photocatalyzed oxidation in zeolite cages [J].

Blatter, F ;

Sun, H ;

Vasenkov, S ;

Frei, H .

CATALYSIS TODAY, 1998, 41 (04) :297-309

[3] The mechanism of phenol formation in the Dow Phenol Process [J].

Buijs, W .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) :237-246

[4] Reaction path sampling of the reaction between iron(II) and hydrogen peroxide in aqueous solution [J].

Ensing, B ;

Baerends, EJ .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (34) :7902-7910

[5] A Car-Parrinello study of the formation of oxidizing intermediates from Fenton's reagent in aqueous solution [J].

Ensing, B ;

Buda, F ;

Blöchl, PE ;

Baerends, EJ .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (15) :3619-3627

[6]

Ensing B, 2001, ANGEW CHEM INT EDIT, V40, P2893, DOI 10.1002/1521-3773(20010803)40:15<2893::AID-ANIE2893>3.0.CO

[7]

2-B

[8]

Raja R, 2000, ANGEW CHEM INT EDIT, V39, P2313, DOI 10.1002/1521-3773(20000703)39:13<2313::AID-ANIE2313>3.0.CO

[9]

2-Z

[10] Bifunctional molecular sieve catalysts for the benign ammoximation of cyclohexanone:: One-step, solvent-free production of oxime and ε-caprolactam with a mixture of air and ammonia [J].

Raja, R ;

Sankar, G ;

Thomas, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8153-8154

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