Alkylation of nitrogen heterocycles with 1,3-bis(hydroxymethyl)ferrocene. Generation of the ferrocene dicarbocation [{1,3-(CH2)2C5H3}Fe(C5H5)]2+

被引：3

作者：

Panov, D. M. ^{[1
]}

Polezhaev, A. V. ^{[1
]}

Polukeev, A. V. ^{[1
]}

Petrovskii, P. V. ^{[1
]}

Koridze, A. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] I Javakhishvili Tbilisi State Univ, Inst Metalloorgan Chem, GE-0128 Tbilisi, Georgia

来源：

RUSSIAN CHEMICAL BULLETIN | 2010年 / 59卷 / 11期

关键词：

ferrocene; (ferrocene-1,3-diyl)dimethylium; imidazole; pyrrole; ferrocenylmethylation; PINCER COMPLEXES; PALLADIUM;

D O I：

10.1007/s11172-010-0361-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The alkylation of imidazole and 5-benzyloxycarbonyl-3,4-diethylpyrrole with 1,3-bis-(hydroxymethyl)ferrocene (1) afforded bis-imidazole (4) and bis-pyrrole (7) derivatives of ferrocene, respectively. The reaction of diol 1 with trifluoroacetic acid gave the dicarbocationic complex [{1,3-(CH2)(2)C5H3}Fe(C5H5)](2+) (2) characterized by H-1 NMR spectroscopy.

引用

页码：2098 / 2101

页数：4

共 16 条

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