Alkylation of nitrogen heterocycles with 1,3-bis(hydroxymethyl)ferrocene. Generation of the ferrocene dicarbocation [{1,3-(CH2)2C5H3}Fe(C5H5)]2+

被引：3
作者：
Panov, D. M. [1 ]
Polezhaev, A. V. [1 ]
Polukeev, A. V. [1 ]
Petrovskii, P. V. [1 ]
Koridze, A. A. [1 ,2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] I Javakhishvili Tbilisi State Univ, Inst Metalloorgan Chem, GE-0128 Tbilisi, Georgia
来源：
RUSSIAN CHEMICAL BULLETIN | 2010年 / 59卷 / 11期
关键词：
ferrocene; (ferrocene-1,3-diyl)dimethylium; imidazole; pyrrole; ferrocenylmethylation; PINCER COMPLEXES; PALLADIUM;
D O I：
10.1007/s11172-010-0361-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The alkylation of imidazole and 5-benzyloxycarbonyl-3,4-diethylpyrrole with 1,3-bis-(hydroxymethyl)ferrocene (1) afforded bis-imidazole (4) and bis-pyrrole (7) derivatives of ferrocene, respectively. The reaction of diol 1 with trifluoroacetic acid gave the dicarbocationic complex [{1,3-(CH2)(2)C5H3}Fe(C5H5)](2+) (2) characterized by H-1 NMR spectroscopy.
引用
收藏
页码：2098 / 2101
页数：4
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