Fixation and Release of Intact E4 Tetrahedra (E = P, As)

被引：57

作者：

Spitzer, Fabian ^{[1
]}

Sierka, Marek ^{[2
]}

Latronico, Mario ^{[5
]}

Mastrorilli, Piero ^{[5
]}

Virovets, Alexander V. ^{[3
,4
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] Univ Jena, Otto Schott Inst Mat Forsch, D-07745 Jena, Germany

[3] Nikolaev Inst Inorgan Chem SB RAS, Novosibirsk, Russia

[4] Novosibirsk State Univ, Novosibirsk 630090, Russia

[5] Dipartimento Ingn Civile Ambientale Terr Edile &, Bari, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 14期

关键词：

arsenic; density functional calculations; main-group chemistry; NMR spectroscopy; phosphorus; SYMMETRICAL P-4 CLEAVAGE; WHITE PHOSPHORUS; TETRAPHOSPHORUS COMPLEXES; ELECTRON-DIFFRACTION; METAL-COMPLEXES; ACTIVATION; LIGAND; RUTHENIUM; HYDROLYSIS; MOLECULES;

D O I：

10.1002/anie.201411451

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the reaction of [NacnacCuCH(3)CN] with white phosphorus (P-4) and yellow arsenic (As-4), the stabilization and enclosure of the intact E-4 tetrahedra are realized and the disubstituted complexes [(NacnacCu)(2)(mu,eta(2:2)-E-4)] (1a: E=P, 1b: E=As) are formed. The mono-substituted complex [NacnacCu(eta(2)-P-4)] (2), was detected by the exchange reaction of 1a with P-4 and was only isolated using low-temperature work-up. All products were comprehensively spectroscopically and crystallographically characterized. The bonding situation in the products as intact E-4 units (E=P, As) was confirmed by theory and was experimentally proven by the pyridine promoted release of the bridging E-4 tetrahedra in 1.

引用

页码：4392 / 4396

页数：5

共 52 条

[21] Complexes with a monohapto bound phosphorus tetrahedron and phosphaalkyne [J].

Gröer, T ;

Baum, G ;

Scheer, M .

ORGANOMETALLICS, 1998, 17 (26) :5916-5919

[22]

Heinl, 2013, ANGEW CHEM, V125, P11087

[23]

Heinl S., 2014, ANGEW CHEM, V126, P7769

[24] Selective Functionalization of P4 by Metal-Mediated C-P Bond Formation [J].

Heinl, Sebastian ;

Reisinger, Sabine ;

Schwarzmaier, Christoph ;

Bodensteiner, Michael ;

Scheer, Manfred .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (29) :7639-7642

[25] Intact P4 Tetrahedra as Terminal and Bridging Ligands in Neutral Complexes of Manganese [J].

Heinl, Sebastian ;

Peresypkina, Eugenia V. ;

Timoshkin, Alexey Y. ;

Mastrorilli, Piero ;

Gallo, Vito ;

Scheer, Manfred .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (41) :10887-10891

[26] Activation of phosphorus by group 14 elements in low oxidation states [J].

Khan, Shabana ;

Sen, Sakya S. ;

Roesky, Herbert W. .

CHEMICAL COMMUNICATIONS, 2012, 48 (16) :2169-2179

[27]

Krossing I, 2002, CHEM-EUR J, V8, P700, DOI 10.1002/1521-3765(20020201)8:3<700::AID-CHEM700>3.0.CO

[28]

2-C

[29]

Lapinte C., 2001, ANGEW CHEM INT EDIT, V113, P4028, DOI DOI 10.1002/1521-3773(20011015)40:203.0.CO

[30]

2-2

← 1 2 3 4 5 6 →