cis-Bis(2,2′-bipyrimidine-κ2 N 1,N 1′)dibromidomanganese(II) nitromethane monosolvate

被引：2

作者：

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811010075

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [MnBr2(C8H6N4)(2)]center dot CH3NO2, contains one half of a neutral MnII complex and one half of a nitromethane solvent molecule, the complete molecules being generated by the application of twofold symmetry. In the complex, the MnII ion has a distorted cis-Br2N4 octahedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br- ions. There are intra- and intermolecular C-H...Br and C-H...N contacts.

引用

页码：M474 / U785

页数：10

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