cis-Bis(2,2′-bipyrimidine-κ2 N 1,N 1′)dibromidomanganese(II) nitromethane monosolvate

被引：2
作者：
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811010075
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [MnBr2(C8H6N4)(2)]center dot CH3NO2, contains one half of a neutral MnII complex and one half of a nitromethane solvent molecule, the complete molecules being generated by the application of twofold symmetry. In the complex, the MnII ion has a distorted cis-Br2N4 octahedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br- ions. There are intra- and intermolecular C-H...Br and C-H...N contacts.
引用
收藏
页码：M474 / U785
页数：10
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