cis-Bis(2,2′-bipyrimidine-κ2 N 1,N 1′)dibromidomanganese(II) nitromethane monosolvate

被引：2

作者：

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811010075

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [MnBr2(C8H6N4)(2)]center dot CH3NO2, contains one half of a neutral MnII complex and one half of a nitromethane solvent molecule, the complete molecules being generated by the application of twofold symmetry. In the complex, the MnII ion has a distorted cis-Br2N4 octahedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br- ions. There are intra- and intermolecular C-H...Br and C-H...N contacts.

引用

页码：M474 / U785

页数：10

共 7 条

[1]

Bruker, 2000, SAINT and SADABS

[2]

Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

[3] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[4] Synthesis, structure and magnetic properties of mononuclear [Mn(2,2'-bipyrimidine)(2)(H2O)(2)][ClO4](2) and polynuclear [Mn(2,2'-bipyrimidine)(NO3)(2)] complexes [J].

Hong, DM ;

Wei, HH ;

Gan, LL ;

Lee, GH ;

Wang, Y .

POLYHEDRON, 1996, 15 (14) :2335-2340

[5] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[6] New approaches to magnetic clusters with hexacyanometallate building blocks [J].

Smith, JA ;

Galán-Mascarós, JR ;

Clérac, R ;

Sun, JS ;

Xiang, OY ;

Dunbar, KR .

POLYHEDRON, 2001, 20 (11-14) :1727-1734

[7] Structure validation in chemical crystallography [J].

Spek, Anthony L. .

ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155

← 1 →