Two Novel Lanthanide Coordination Polymers: Synthesis, Structures, Fluorescence, and Thermal Properties

被引：0

作者：

Li, Zifeng ^{[1
]}

Zhu, Kaiyue ^{[1
]}

Yan, Lihua ^{[1
]}

Li, Gang ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2010年 / 40卷 / 10期

基金：

芬兰科学院; 中国国家自然科学基金;

关键词：

coordination polymers; crystal structures; fluorescence properties; thermal properties; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; COMPLEXES; LUMINESCENCE; NETWORKS; TB(III); GD(III); LAYER;

D O I：

10.1080/15533174.2010.522537

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel 1-D chain lanthanide coordination polymers, {[Pr(2-L)2(2-NO3)(CH3OH)(H2O)2]center dot H2O}n (1) and {[Ho(2-L)2(2-NO3)(CH3OH)(H2O)]center dot H2O}n (2) (HL = N-benzoyl-N'-(4-benzoxy)thiourea) have been prepared and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The fluorescence properties and themostabilities of the two polymers were determined as well.

引用

页码：739 / 747

页数：9

共 36 条

[1] Experimental and theoretical vibrational study of tetraaquatris(succinate)diholmium(III) hexahydrate, a bidimensional hybrid coordination polymer [J].

Bernini, M. C. ;

Garro, J. C. ;

Brusau, E. V. ;

Narda, G. E. ;

Varetti, E. L. .

JOURNAL OF MOLECULAR STRUCTURE, 2008, 888 (1-3) :113-123

[2] Coordination Polymers Versus Metal-Organic Frameworks [J].

Biradha, Kumar ;

Ramana, Arunachalam ;

Vittal, Jagadese J. .

CRYSTAL GROWTH & DESIGN, 2009, 9 (07) :2969-2970

[3] A lanthanide-based helicate coordination polymer derived from a rigid monodentate organic bridge synthesized in the solid state [J].

Bucar, Dejan-Kresimir ;

Papaefstathiou, Giannis S. ;

Hamilton, Tamara D. ;

MacGillivray, Leonard R. .

NEW JOURNAL OF CHEMISTRY, 2008, 32 (05) :797-799

[4] Microporous metal - Organic frameworks formed in a stepwise manner from luminescent building blocks [J].

Chandler, Brett D. ;

Cramb, David T. ;

Shimizu, George K. H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (32) :10403-10412

[5] Silver coordination polymers - From simple complexes to functional networks [J].

Constable, EC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (01) :1-2

[6]

Czakis-Sulikowska D, 2009, POL J CHEM, V83, P1893

[7] Isophthalato-based 2D coordination polymers of Eu(III), Gd(III), and Tb(III): Enhancement of the terbium-centered luminescence through thiophene derivatization [J].

de Bettencourt-Dias, A .

INORGANIC CHEMISTRY, 2005, 44 (08) :2734-2741

[8] Exploring lanthanide luminescence in metal-organic frameworks: Synthesis, structure, and guest-sensitized luminescence of a mixed europium/terbium-adipate framework and a terbium-adipate framework [J].

de Lill, Daniel T. ;

de Bettencourt-Dias, Ana ;

Cahill, Christopher L. .

INORGANIC CHEMISTRY, 2007, 46 (10) :3960-3965

[9] A two-dimensional holmium(III) coordination polymer:: poly[amino-tris(μ-4-aminobenzoato)holmium(III)] [J].

Feng, Yong-Lan ;

Xu, Jin-Sheng ;

Kuang, Dai-Zhi ;

Peng, Yun-Lin .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2338-U843

[10] Coordination of biologically important α-amino acids to calcium(II) at high pH:: Insights from crystal structures of calcium α-aminocarboxylates [J].

Fox, Stefan ;

Buesching, Insa ;

Barklage, Walter ;

Strasdeit, Henry .

INORGANIC CHEMISTRY, 2007, 46 (03) :818-824

← 1 2 3 4 →