Dimethyl(4′-pyridyl-2,2′:6′,2"-terpyridine-κ3N1,N1′,N1")bis(thiocyanato-κN)tin(IV)

被引:5
作者
Najafi, Ezzatollah [2 ]
Amini, Mostafa M. [2 ]
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
D O I
10.1107/S1600536811001309
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Sn atom in the title compound, [Sn(CH3)(2)(NCS)(2)(C20H14N4)], is N,N',N ''-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C2SnN5 pentagonal-bipyramidal geometry [C-Sn-C = 173.66 (8)degrees] with the methyl groups in axial and the N atoms in equatorial positions.
引用
收藏
页码:M211 / U937
页数:10
相关论文
共 5 条
[1]  
Agilent, 2010, CRYSALIS PRO
[2]  
Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]
[3]   CRYSTAL AND MOLECULAR-STRUCTURE OF DIMETHYLDIISOTHIOCYANATO(TERPYRIDYL)TIN(IV) [J].
NAIK, DV ;
SCHEIDT, WR .
INORGANIC CHEMISTRY, 1973, 12 (02) :272-276
[4]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[5]   publCIF: software for editing, validating and formatting crystallographic information files [J].
Westrip, Simon P. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925