Analysis of the trace amount of metallic elements in iron and steels using the microwave decomposition by ICP-AES and ICP-MS

被引：9
作者：
Hanada, K
Kajima, Y
Fujimoto, K
Shimura, M
Satoh, S
机构：
[1] JFE Steel Corp, Steel Res Labs, Chuo Ku, Chiba 2600835, Japan
[2] JFE Steel Corp, Technol Planning Dept, Chiba 2600835, Japan
来源：
TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN | 2003年 / 89卷 / 09期
关键词：
trace analysis; determination; decomposition under pressure; external heating; sample preparation; microwave heating; oxide; alumina; aluminum; calcium oxide; total amount; iron; steel; EXCHANGE CHROMATOGRAPHY; SPECTROMETRY; BASE;
D O I：
10.2355/tetsutohagane1955.89.9_895
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
Trace amount of metallic elements as At, Ca and Mn, which form oxides in iron and steels. were determined by ICP-AES and ICP-MS after the decomposition of samples using HF/HCl/HNO3 under microwave irradiation. The oxides in iron and steels, which were extracted by using Br-2-CH3OH extraction, could be decomposed by two-steps acid decomposition using H2SO4 followed by addition of HF in a pressurized vessel at elevated temperatures. The limits of detection for At, Ca, Mg, Mn, Cr, Ni, Cu, Zn and Co by microwave decomposition/ICP-MS were 0.01 similar to 0.36 ppm.
引用
收藏
页码：895 / 899
页数：5
相关论文
共 50 条
[41]   Analysis of Macroelements, Beneficial Trace Elements, Rare Earth Elements in the Wild Ixeris Chinensis (Thunb.) Nakai by ICP-MS [J].
Rui, Yukui .
ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (14) :8231-8232
[42]   A preliminary study of the concentration of metallic elements in the blood of patients with multiple sclerosis as measured by ICP-MS [J].
de Oliveira, Marcela ;
Ribeiro Gianeti, Thiago Marcelo ;
Gomes da Rocha, Fernando Coronetti ;
Lisboa-Filho, Paulo Noronha ;
Piacenti-Silva, Marina .
SCIENTIFIC REPORTS, 2020, 10 (01)
[43]   Microwave-induced combustion method for the determination of trace and ultratrace element impurities in graphite samples by ICP-OES and ICP-MS [J].
Cruz, Sandra M. ;
Schmidt, Lucas ;
Dalla Nora, Flavia M. ;
Pedrotti, Matheus F. ;
Bizzi, Cezar A. ;
Barin, Juliano S. ;
Flores, Erico M. M. .
MICROCHEMICAL JOURNAL, 2015, 123 :28-32
[44]   Microchip-Based Liquid Liquid Extraction Using Isotope Dilution ICP-MS for Trace Copper Determination in Steels [J].
Kagawa, Tsuyoshi ;
Ohno, Masashi ;
Seki, Tatsuya ;
Chikama, Katsumi .
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2010, 17 :111-119
[45]   Microwave-induced combustion for further determination of potentially toxic elements in honey by ICP-MS [J].
Cauduro, Vitoria H. ;
Alves, Camila M. A. C. ;
Nascimento, Mariele S. ;
Druzian, Gabriel T. ;
Balbinot, Fernanda P. ;
Mesko, Marcia F. ;
Flores, Erico M. M. .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2024, 416 (11) :2859-2870
[46]   Microwave-induced combustion for further determination of potentially toxic elements in honey by ICP-MS [J].
Vitoria H. Cauduro ;
Camila M. A. C. Alves ;
Mariele S. Nascimento ;
Gabriel T. Druzian ;
Fernanda P. Balbinot ;
Marcia F. Mesko ;
Erico M. M. Flores .
Analytical and Bioanalytical Chemistry, 2024, 416 :2859-2870
[47]   Determination of essential and trace elements in various vegetables using ICP- MS [J].
Ali, Rasul Jameel ;
Sadee, Bashdar Abuzed .
BAGHDAD SCIENCE JOURNAL, 2023, 20 (03) :715-725
[48]   Sensitivity Improvement Mechanism of the Mistral Desolvating Sample Introduction to ICP-MS/AES and Its Application to Steel Analysis [J].
Itabashi, Daisuke ;
Mizukami, Kazumi ;
Aimoto, Michihiro ;
Nishifuji, Masayuki .
ISIJ INTERNATIONAL, 2018, 58 (06) :1061-1068
[49]   Trace impurity analysis in uranium materials by rapid separation and ICP-MS/MS measurement with matrix matched external calibration [J].
Ni, Youyi ;
Bu, Wenting ;
Xiong, Ke ;
Ding, Xiaotong ;
Wang, Hai ;
Liu, Xuemei ;
Long, Kaiming ;
Hu, Sheng .
MICROCHEMICAL JOURNAL, 2021, 169
[50]   Determination of bromine and iodine in shrimp and its parts by ICP-MS after decomposition using microwave-induced combustion [J].
Hartwig, Carla Andrade ;
Toralles, Isis Goncalves ;
Crizel, Marcelo Guerreiro ;
Hermes Muller, Aline Lima ;
Picoloto, Rochele Sogari ;
Moraes Flores, Erico Marlon ;
Mesko, Marcia Foster .
ANALYTICAL METHODS, 2014, 6 (18) :7540-7546
12345